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World No. 1 Nadal rescued his country as he joined forces with Marcel Granollers to win the deciding doubles rubber of their quarterfinal against Argentina and set up a clash with Britain who beat Germany 2-0.
The world number one almost single-handedly hauled his country home and set up a final with Canada in the inaugural edition of the revamped competition on Sunday.
Sevilla beat city rivals Real Betis 2-0 on Thursday with the help of a controversial penalty and a touch of class from Argentine winger Lucas Ocampos.
The win takes Barca on to 61 points after 28 games, five clear of nearest challengers Real Madrid, who host Eibar on Sunday in their first game back.
Spain scored a stoppage-time equaliser through Jose Luis Gaya to rescue a 1-1 draw away to Germany.
He was instrumental in Las Palmas' promotion to the La Liga during the 2015-16 season when he captained the side against Spanish giants Barcelona and Real Madrid.
Ilkay Gundogan gave Joachim Loew's side the perfect start with a clinical goal in the 14th minute but Silvan Widmer earned their smaller neighbours a deserved draw just before the hour.
A day after the Spanish club reaffirmed its position not to facilitate a transfer, Messi's father-agent did not dismiss the possibility of his son reconsidering his decision to leave.
Germany were powerless to stop Luis Enrique's relentless side as the visitors suffered their worst defeat in a competitive game and the most humiliating since losing by the same scoreline against Austria in a friendly in 1931.
The former Real Madrid skipper had called time on his five-year spell with side Porto in July after his contract with the Portuguese club expired.
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