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PSG will face Borussia Dortmund in the semifinals after the Germans beat Atletico Madrid.
PSG came into the match unbeaten in their last 27 games in all competitions but were undone by a fired-up Barcelona side looking to return the club to the summit of European football.
With seven games remaining in the neck-and-neck title race, Liverpool and Arsenal have 71 points with the Gunners leading on goal difference. Holders Manchester City are third on 70 points, while United are sixth.
Cabo da Roca is the westernmost point of the Sintra Mountain Ranges, mainland Portugal, continental Europe as well as the Eurasian landmass.
Rubiales was returning to Spain amid a judicial probe into the business deal to hold the Spanish Super Cup in Saudi Arabia.
Liverpool claimed a 2-1 comeback victory over Bright.n & Hove Albion.
Prosecutor Marta Durantez charged Rubiales with one count of sexual assault and one of coercion for his alleged actions in the aftermath of the kiss, offences carrying jail terms of one year and 18 months, respectively.
Liverpool are second with 64 points, behind the Gunners on goal difference, with 10 games remaining of a thrilling three-way title race..
Liverpool's patched-up side came out after the break in top gear.
Disciplined Lazio stifled the German side's attacks and Bayern were toothless throughout, failing to get a single effort on target in the match.