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The players, who are not minors, were later released following a court decision and after the data on their mobile phones was seized.
The practices have allowed PSG, owned by Qatar Sports Investments since 2011, to sign top players and coaches 'well above its potential in a normal market situation', LaLiga alleges in the complaint filed on Saturday.
Alex Sanchez, 34, is the third foreigner to be recruited by Gokulam this season.
The arrests come a day after football federation chief Luis Rubiales said Spanish soccer has a racism problem, following a race-crime complaint lodged by Real Madrid.
Barca were the better side and earned a well deserved win against a Real Madrid side that at times seemed resigned to their fate.
Goalkeeper Yassine Bounou played in Kochi in a pre-season friendly for Girona FC in 2018.
Real returned to the top of La Liga table after their 4-1 victory.
Real Madrid sit top of the table on nine points, level with Real Betis. Barcelona and Villarreal are right behind on seven points, with Osasuna and Real Sociedad on six.
The win also made their Italian coach Carlo Ancelotti the first manager to capture titles in each of Europe’s top five leagues — England, Spain, Germany, Italy and France.
The Catalan club will play next season's games at an almost full-capacity Camp Nou but will relocate to the Olympic Stadium in Montjuic for the following campaign.