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The national prosecutor's office said Spain's football federation boss Luis Rubiales could face criminal charges in addition to the ongoing 'serious misconduct' enquiry.
Montse Tome, who was Vilda's assistant since 2018, becomes the first woman to helm the women's national team.
Alejandro Blanco has said Rubiales' gesture cannot be tolerated.
Angeles Bejar had locked herself in a church in her hometown of Motril in southern Spain to protest the treatment of her son in a furore over kissing World Cup player Jenni Hermoso
The soccer federation's regional representatives late on Monday demanded the immediate resignation of Rubiales, but stopped short of proposing a motion of no confidence, and called for a restructuring of leadership
A spokesperson for the prosecutor's office said the court had received several complaints but would launch a full inquiry only if Hermoso sought one
In a joint statement, all 23 of the cup-winning squad including Hermoso, as well as 32 other squad members, said they would not play internationals while Rubiales remains head of the Royal Spanish Football Federation
Luis Rubiales kissed the player during celebrations after Spain's World Cup triumph.
Carmona scored a 29th-minute goal to earn Spain a 1-0 win over England as they secured their first Women's World Cup title
The Matildas won 2-0 with Caitlin Foord and Hayley Raso among the scorers.