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Rakshit Dagar saved a couple of penalties in the shootout to do the star turn.
Pele has suffered from a series of health issues in recent years.
Six teams are in the fray and a total of 30 matches will be played in a double-leg format in the KWL.
Benfica qualified as group runners-up with a win over bottom club Dynamo Kyiv.
Kerr showed skills more in keeping with the Australian Rules code she played as a child when she barged into the fan who had run onto the Kingsmeadow pitch late in Wednesday's game, leaving him in a heap on the ground.
Hyderabad FC recorded their first win against Bengaluru FC.
Atletico won 3-1 at Porto in a tense, ill-tempered game as both sides finished with 10 men.
The Indian defender, who now plays in Croatia, made the announcement on social media.
SC East Begal are the lone team yet to win a match this season.
The win took Jamshedpur to the second spot as Bagan slumped to fifth place.
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