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The Champions League final, which Real Madrid won 1-0, was delayed by more than half an hour after police tried to hold off people trying to force their way into the ground. Some fans, including children, were tear-gassed by French riot police.
The Brazilian defender is the most decorated player in Real's 120-year history, picking up his 25th trophy with the club as they beat Liverpool 1-0 in the Champions League final on Saturday.
Mbappe was widely tipped for a move to the Spanish capital but signed a contract extension until 2025 at PSG last week in a dramatic U-turn, a decision that irked many Real players and fans.
Liverpool were looking for their seventh European Cup triumph but despite their best efforts they were left in awe of Courtois's sublime performance.
The 30-year-old underlined his full commitment to Liverpool for the final, which is a rematch of the 2018 title decider won 3-1 by Real Madrid in Kyiv.
Mbappe had been widely tipped to join Real Madrid this summer but stunned the Spanish champions by signing a contract extension until 2025 with PSG last week.
It was another superb rearguard action by Real who came from behind for the third consecutive time in this season Champions League knockout stage.
The win also made their Italian coach Carlo Ancelotti the first manager to capture titles in each of Europe’s top five leagues — England, Spain, Germany, Italy and France.
Liverpool did enough to build themselves a solid lead for Tuesday's return game in Spain where they will be confident of finishing off the job.
Chelsea had looked on course to complete an astonishing comeback after taking a 3-0 lead in their quarter-final second leg with goals from Mason Mount, Antonio Rudiger and an excellent individual effort from Timo Werner.