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Kerala Blasters fought bravely with 10 men against Mumbai City for the most the second half but were beaten by an 89th minute own goal in their crucial Super Cup group match in Goa on Thursday.
Peprah scored the winner in the 52nd minute to give the Blasters a 1-0 win over Mumbai City FC.
Kerala Blasters will host Mumbai City FC in Kochi on March 7.
Kerala Blasters lost 2-4 after Kwame Peprah was sent off for celebrating his equaliser against Mumbai City.
Mumbai City scored twice in a 4-2 win after Kwame Peprah's sending off shortly after the game was level at 2-2.
Jimenez has scored in three consecutive matches for Kerala Blasters in the ISL.
Kerala Blasters were unbeaten in all three of their away matches this season in the ISL.
Thaer Krouma scored a late equaliser as City came back from 0-2 to make it 2-2.
Blasters, who thrashed Mumbai City FC 8-0 in their opening match, have four points from two matches. Punjab too have four points from two outings.
Noah Sadaoui and Kwame Peprah scored hat-tricks for the Yellow Brigade.
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