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Van Dijk was given the captain's armband by Liverpool on a permanent basis in 2023.
Virgil Van Dijk scored a late winner in a 2-1 victory for Liverpool over West Ham at Anfield.
Arsenal suffered a minor first-half setback after their exhilarating 3-0 Champions League quarter-final first-leg victory over visiting Real Madrid in midweek.
The 32-year-old, who joined the club in 2017 from AS Roma, could have left the league leaders for free in the summer with his contract expiring in June.
The French striker missed a penalty in Real Madrid's 2-0 defeat to Liverpool at Anfield.
Manchester City and Arsenal suffered shock defeats in the tenth round.
Diaz scored more Premier League goals against United than any other opponent.
Every team will play eight games against different opponents in the new format of Europe's elite club competition.
Diogo Jota opened the scoring in a 2-0 win against newly-promoted Ipswich Town.
The Dutchman was in charge of Eredivisie side Feyenoord.
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