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A new US peace proposal would see Kyiv ceding land and more than halving its army according to sources.
The new sanctions were unveiled one day after plans for a summit between Trump and Putin fell apart.
Despite ongoing fighting, diplomatic efforts continue, focusing on a summit between Putin and Trump in Alaska.
This summit aims to address the conflict, but Zelenskyy insists on European involvement, while Trump threatens new sanctions against Russia.
A US official said Yermak was scheduled to meet with US Secretary of State Marco Rubio on Wednesday.
Trump later responded in terms critical of Putin.
The direct appeal to Putin came after Ukrainian President Volodymyr Zelensky urged his allies to put Russia under more pressure to halt its invasion.
US officials were frustrated by Ukrainian President Zelenskiy's comment this week that Trump's special envoy, Steve Witkoff, was "spreading Russian narratives."
Russian ballistic missiles slammed into the heart of the northern Ukrainian city of Sumy.
Russia has used Iranian drones as well as North Korean missiles and artillery shells on the war front.
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