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In a low-scoring thriller, the Indian women fought hard until the end but paid the price for poor batting.
Wong went ballistic on a turning track at the Wankhede Stadium, scoring her last 23 runs off only seven balls.
Shreyanka Patil (2/26) gave away only 10 while defending 13 in the final over as the home side took a 1-0 lead in the three-match series.
The 24-year-old made her international debut in the T20I series against Bangladesh in July.
Put in to bat Pakistan 'A ' made 352/8 with Tayyab Tahir scoring 108.
Bengal's Abhimanyu Easwaran will lead India A against Bangladesh A in the two four-day matches.
Despite opener Dane Cleaver's fighting 83, the Kiwis were bowled out for 178 in 38.3 overs. Medium-pacer Raj Bawa picked up 4/11.
India sealed the three-match series with a four-wicket win in Chennai.
The Sanju Samson-led India A posted a 7-wicket win in the first unofficial ODI in Chennai.
India's U-19 World Cup star Raj Angad Bawa has earned his maiden India A call-up.